Product ID:S-261 SODIUM CARBONATE CALCINED DRY
MSDS Date:10/05/1990
FSC:6810
NIIN:00F025819
MSDS Number: BPSVV

Emergency Phone: 201-796-7100

Info Phone: 201-796-7100

Cage: 1B464

Telephone: 201-796-7100

Cage: 1B464

SODIUM CARBONATE (SODA ASH, TRONA, CARBONIC ACID, CRYSTOL

CAS: 497-19-8

RTECS: VZ4050000

Fraction By Weight: 100%

LD50 LC50 Mixture:ORAL LD50 (RAT): 4090 MG/KG
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHALATION: TOXIC/MUCOUS MEMBRANE
IRRITATION/COUGH/BREATH SHORTNESS/GASTROINTESTINAL CHANGE. SKIN:
IRRITATION/RED/ERYTHEMA/BLISTER/NECROSIS. EYE:
IRRITATION/RED/PAIN/BLURRY VISION/TEMPORARY CORNEAL EP ITHELIUM
DAMAGE/NECROSIS. INGESTION: GASTRIC MUCOSA CORROSION/SORE
THROAT/NAUSEA/VOMIT/ABDOMINAL PAIN/TOXIC/DIARRHEA.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:INHALATION: PERFORATION OF THE NASAL SEPTUM.
SKIN: DERMATITIS & POSSIBLE SODA ULCERS OF THE HANDS & WRISTS,
SENSITIVITY. EYES: IRRITATION, REDNESS, PAIN, BLURRED VISION,
TEMPORARY DAMAGE OF CORNEAL EP ITHELIUM, NECROSIS. INGESTION: DEATH
ISGENERALLY DUE TO CIRCULATORY COLLAPSE. LETHAL HUMAN DOSE: 30
GRAMS.

First Aid:INHALATION: REMOVE TO FRESH AIR. GIVE CPR. KEEP WARM/QUIET.
SKIN: WASH W/SOAP/MILD DETERGENT/WATER FOR 15-20 MIN. EYE: FLUSH
W/WATER FOR 15-20 MIN. USE NORMAL SALINE FOR 30-60 MIN. COVER
W/STERILE BAN DAGE. INGESTION: DILUTE W/WATER/MILK. AVOID GASTRIC
LAVAGE/EMETIC. USE ESOPHAGOSCOPY TO AVOID CORROSION. TREAT SHOCK.
KEEP HEAD BELOW HIPS TO PREVENT ASPIRATION. OBTAIN MEDICAL
ATTENTION IN ALL CASES.

Extinguishing Media:DRY CHEMICAL/CO2/WATER SPRAY/REGULAR FOAM. FOR
LARGE FIRES USE WATER SPRAY/FOG/REGULAR FOAM.
Fire Fighting Procedures:MOVE CONTAINER FROM FIRE AREA IF POSSIBLE.
AVOID BREATHING VAPORS OR DUSTS. KEEP UPWIND. WEAR SELF-CONTAINED
BREATHING APPARATUS W/FULL FACEPIECE.
Unusual Fire/Explosion Hazard:NEGLIGIBLE FIRE HAZARD WHEN EXPOSED TO
HEAT OR FLAME.

Spill Release Procedures:SWEEP UP & PLACE IN SUITABLE (FIBERBOARD)
CONTAINERS FOR RECLAMATION OR LATER DISPOSAL.

Handling and Storage Precautions:STORE AWAY FROM INCOMPATIBLE
SUBSTANCES.
Other Precautions:AVOID CONTACT W/EYES & SKIN.

Respiratory Protection:DUST/MIST/AIR-PURIFYING FULL FACEPIECE/POWERED
AIR-PURIFYING/TYPE C SUPPLIED-AIR/SCBA W/HIGH EFFICIENCY
PARTICULATE FILTER/TIGHT-FITTING FACEPIECE & HIGH EFFICIENCY
PARTICULATE FILTER/HELMET/HOOD OPER ATED IN POSITIVE PRESSURE MODE.
Ventilation:LOCAL EXHAUST OR GENERAL DILUTION VENTILATION SYSTEM
Protective Gloves:REQUIRED
Eye Protection:SPLASH-PROOF/DUST-RESISTANT GOGGLES
Other Protective Equipment:EYE WASH FOUNTAIN, QUICK DRENCH SHOWER,
IMPERVIOUS CLOTHING & EQUIPMENT
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING & SHOES
BEFORE REUSE.
Supplemental Safety and Health
NOTE TO PHYSICIAN: NO SPECIFIC ANTIDOTE. TREAT SYMPTOMATICALLY &
SUPPORTIVELY.

Boiling Pt:B.P. Text:DECOMPOSES
Melt/Freeze Pt:M.P/F.P Text:1564F/851C
Spec Gravity:2.536
pH:11.5
Solubility in Water:7.1%
Appearance and Odor:ODORLESS/COLORLESS TO WHITE/HYGROSCOPIC SMALL
CRYSTALLINE POWDER/GRANULES

Stability Indicator/Materials to Avoid:YES
WATER, ACIDS, METALS
Stability Condition to Avoid:HEAT, FLAME
Hazardous Decomposition Products:TOXIC SODIUM OXIDE & TOXIC CO & CO2

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE, &
FEDERAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.